A systematic study of Rayleigh-Brillouin scattering in air, N2 and O2 gases

Spontaneous Rayleigh-Brillouin scattering experiments in air, N2 and O2 have been performed for a wide range of temperatures and pressures at a wavelength of 403 nm and at a 90 degrees scattering angle. Measurements of the Rayleigh-Brillouin spectral scattering profile were conducted at high signal-to-noise ratio for all three species, yielding high-quality spectra unambiguously showing the small differences between scattering in air, and its constituents N2 and O2. Comparison of the experimental spectra with calculations using the Tenti S6 model, developed in 1970s based on linearized kinetic equations for molecular gases, demonstrates that this model is valid to high accuracy. After previous measurements performed at 366 nm, the Tenti S6 model is here verified for a second wavelength of 403 nm. Values for the bulk viscosity for the gases are derived by optimizing the model to the measurements. It is verified that the bulk viscosity parameters obtained from previous experiments at 366 nm, are valid for wavelengths of 403 nm. Also for air, which is treated as a single-component gas with effective gas transport coefficients, the Tenti S6 treatment is validated for 403 nm as for the previously used wavelength of 366 nm, yielding an accurate model description of the scattering profiles for a range of temperatures and pressures, including those of relevance for atmospheric studies. It is concluded that the Tenti S6 model, further verified in the present study, is applicable to LIDAR applications for exploring the wind velocity and the temperature profile distributions of the Earth's atmosphere. Based on the present findings, predictions can be made on the spectral profiles for a typical LIDAR backscatter geometry, which deviate by some 7 percent from purely Gaussian profiles at realistic sub-atmospheric pressures occurring at 3-5 km altitude in the Earth's atmosphere

Effect of the W-term for a t-U-W Hubbard ladder

Antiferromagnetic and d_{x2-y2}-pairing correlations appear delicately balanced in the 2D Hubbard model. Whether doping can tip the balance to pairing is unclear and models with additional interaction terms have been studied. In one of these, the square of a local hopping kinetic energy H_W was found to favor pairing. However, such a term can be separated into a number of simpler processes and one would like to know which of these terms are responsible for enhancing the pairing. Here we analyze these processes for a 2-leg Hubbard ladder

The Supreme Court As Risk Manager: An Analysis of Skinner

Examining a recent case in which the U.S. Supreme Court approved the collection of blood and urine samples from railroad employees, the authors conclude that, in attempting to improve railroad safety, both majority and minority opinions reflected undue emphasis on technical issues and inadequate attention to the intangible social values underlying traditional Constitutional rights to privacy

The COBE Normalization for Standard CDM

The COBE detection of CMB anisotropies provides the best way of fixing the amplitude of fluctuations on the largest scales. This normalization is usually given for an n=1 spectrum, including only the anisotropy caused by the Sachs- Wolfe effect. This is certainly not a good approximation for a model containing any reasonable amount of baryonic matter. In fact, even tilted S-W spectra are not a good fit to models like CDM. Here we normalize standard CDM (sCDM) to the 2-year COBE data, and quote the best amplitude in terms of the conventionally used measures of power. We also give normalizations for some specific variants of this standard model, and we indicate how the normalization depends on the assumed values of n, Omega_B and H_0. For sCDM we find =19.9\pm1.5uK, corresponding to sigma_8=1.34\pm0.10, with the normalization at large scales being B=(8.16\pm1.04)\times10^5 (Mpc/h)^4, and other numbers given in the Table. The measured rms temperature fluctuation smoothed on 10deg is a little low relative to this normalization. This is mainly due to the low quadrupole in the data: when the quadrupole is removed, the measured value of sigma(10) is quite consistent with the best-fitting . The use of should be preferred over sigma(10), when its value can be determined for a particular theory, since it makes full use of the data.Comment: 4 pages compressed uuencoded postscript. We have corrected an error in our analysi

Diffusion and phase change characterization by mass spectrometry

The high temperature diffusion of trace elements in metals and alloys was investigated. Measurements were made by high sensitivity mass spectrometry in which individual atoms were detected, and quantitative data was obtained for zircaloy-2, 304 stainless steel, and tantalum. Additionally, a mass spectrometer was also an analytical tool for determining an allotropic phase change for stainless steel at 955 C, and a phase transition region between 772 C and 1072 C existing for zircaloy-2. Diffusion rates were measured in thin (0.001" (0.0025 cm) and 0.0005" (0.0013 cm)) ribbons which were designed as high temperature thermal ion sources, with the alkali metals as naturally occurring impurities. In the temperature and pressure regime where diffusion measurements were made, the solute atoms evaporated from the ribbon filaments when the impurities diffused to the surface, with a fraction of these impurity atoms ionized according to the Langmuir-Saha relation. The techniques developed can be applied to many other alloys important to space vehicles and supersonic transports; and, with appropriate modifications, to the diffusion of impurities in composites

A New Source of Reaction - Diffusion Coupling in Confined Systems due to Temperature Inhomogeneity

Diffusion is often accompanied by a reaction or sorption which can induce temperature inhomogeneities. Monte Carlo simulations of Lennard-Jones atoms in zeolite NaCaA are reported with a hot zone presumed to be created by a reaction. Our simulations show that localised hot regions can alter both the kinetic and transport properties. Further, enhancement of the diffusion constant is greater for larger barrier height, a surprising result of considerable significance to many chemical and biological processes. We find an unanticipated coupling between reaction and diffusion due to the presence of hot zone in addition to that which normally exists via concentration.Comment: to be published in Phys. Rev. Let

Microplankton species assemblages at the Scripps Pier from March to November 1983 during the 1982-1984 El Nino event

A semiweekly sampling program at the Scripps Institution of Oceanography pier was begun in 1983 during an El Nino event. Microplankton data for March to November 1983 show a temporal sequence of species assemblages of the 24 important taxa, with a residence time of 1 to 4 weeks. From March to early September, the assemblages consisted of typical neritic taxa. From mid-September to mid-November, the presence of oceanic warm-wave species was associated with positive temperature anomalies characteristic of the El Nino condition. During the period studied numerical abundances were low

Is Cosmology Solved?

We have fossil evidence from the thermal background radiation that our universe expanded from a considerably hotter denser state. We have a well defined and testable description of the expansion, the relativistic Friedmann-Lemaitre model. Its observational successes are impressive but I think hardly enough for a convincing scientific case. The lists of observational constraints and free hypotheses within the model have similar lengths. The scorecard on the search for concordant measures of the mass density parameter and the cosmological constant shows that the high density Einstein-de Sitter model is challenged, but that we cannot choose between low density models with and without a cosmological constant. That is, the relativistic model is not strongly overconstrained, the usual test of a mature theory. Work in progress will greatly improve the situation and may at last yield a compelling test. If so, and the relativistic model survives, it will close one line of research in cosmology: we will know the outlines of what happened as our universe expanded and cooled from high density. It will not end research: some of us will occupy ourselves with the details of how galaxies and other large-scale structures came to be the way they are, others with the issue of what our universe was doing before it was expanding. The former is being driven by rapid observational advances. The latter is being driven mainly by theory, but there are hints of observational guidance.Comment: 13 pages, 3 figures. To be published in PASP as part of the proceedings of the Smithsonian debate, Is Cosmology Solved